前沿科学研究

高性能陶瓷与增材制造团队

High Performance Ceramics and Additive Manufacturing Research Group

A ternary layered rare earth boron-carbon compound Sc2B1.1C3.2 with excellent damage tolerance and electrical conductivity

发布日期:2024年12月16日
作者:高性能陶瓷与增材制造团队

Author: Hao Chen a1, Li Tian ab1, Yawen Guo a, Yueming Li c, Guorui Zhao a

Journal: Journal of the European Ceramic Society

DOI: https://doi.org/10.1016/j.jeurceramsoc.2024.117140

Abstract / 摘要

The exploration of novel ceramic materials with both high strength and damage tolerance has consistently been of paramount importance for advancing the development of ceramics in multiple fields. In this study, a novel ternary layered rare earth boron-carbon compound Sc2B1.1C3.2 was successfully synthesized through an in-situ hot pressing method. The physical and mechanical properties of Sc2B1.1C3.2 were characterized for the first time, encompassing Young’s modulus (228 GPa), shear modulus (94 GPa), bulk modulus (131 GPa), Poisson’s ratio (0.21), Vickers hardness (4.5 ± 0.3 GPa), flexural strength (296 ± 5.8 MPa), fracture toughness (7.03 ± 0.37 MPa·m1/2), electrical conductivity (1.21 ×10−6 Ohm·m), thermal conductivity (23.86 W/(m·K)), heat capacity (0.78 J/(g·K)) and thermal expansion coefficient (7.33 ×10−6 K−1). Remarkably, the high residual strength, damage tolerance factor (Dt) and fracture toughness to strength ratio (KIC/σf) suggest that Sc2B1.1C3.2 has excellent damage tolerance.

Keywords / 关键词

Sc2B1.1C3.2; Ternary layered rare earth boron-carbon compound; Damage tolerance; Conductive ceramics