{"id":898,"date":"2025-10-13T20:16:08","date_gmt":"2025-10-13T12:16:08","guid":{"rendered":"https:\/\/frontbasic.sslab.org.cn\/ecsm\/?p=898"},"modified":"2025-10-13T20:16:08","modified_gmt":"2025-10-13T12:16:08","slug":"%e7%a7%91%e7%a0%94%e8%bf%9b%e5%b1%95-%e9%92%aa%e5%8d%95%e5%8e%9f%e5%ad%90%e6%8e%ba%e6%9d%82%e7%9a%84%e9%87%8d%e6%9e%84%e6%b0%a7%e5%8c%96%e9%93%9c%e7%ba%b3%e7%b1%b3%e7%89%87%e5%ae%9e%e7%8e%b0co","status":"publish","type":"post","link":"https:\/\/frontbasic.sslab.org.cn\/ecsm\/blog\/2025\/10\/13\/%e7%a7%91%e7%a0%94%e8%bf%9b%e5%b1%95-%e9%92%aa%e5%8d%95%e5%8e%9f%e5%ad%90%e6%8e%ba%e6%9d%82%e7%9a%84%e9%87%8d%e6%9e%84%e6%b0%a7%e5%8c%96%e9%93%9c%e7%ba%b3%e7%b1%b3%e7%89%87%e5%ae%9e%e7%8e%b0co\/","title":{"rendered":"\u79d1\u7814\u8fdb\u5c55 |\u00a0\u94aa\u5355\u539f\u5b50\u63ba\u6742\u7684\u91cd\u6784\u6c27\u5316\u94dc\u7eb3\u7c73\u7247\u5b9e\u73b0CO\u2082\u5411\u591a\u78b3\u4ea7\u7269\uff08C\u2082\u208a\uff09\u7684\u9ad8\u6548\u7535\u50ac\u5316\u8f6c\u5316"},"content":{"rendered":"\n

\u5229\u7528\u53ef\u518d\u751f\u80fd\u6e90\u9a71\u52a8\u7535\u50ac\u5316\u4e8c\u6c27\u5316\u78b3\uff08CO2<\/sub>\uff09\u8fd8\u539f\u53ef\u4ee5\u5c06\u5927\u91cf\u4eba\u4e3a\u6392\u653e\u7684CO2<\/sub>\u8f6c\u5316\u4e3a\u4e59\u70ef\u3001\u4e59\u9187\u7b49\u9ad8\u9644\u52a0\u503c\u591a\u78b3\uff08C\u2082\u208a\uff09\u4ea7\u7269\uff0c\u56e0\u6b64\u88ab\u5e7f\u6cdb\u8ba4\u4e3a\u662f\u52a9\u529b\u78b3\u4e2d\u548c\u76ee\u6807\u5b9e\u73b0\u7684\u4e00\u4e2a\u91cd\u8981\u9014\u5f84\u3002\u5b9e\u73b0CO\u2082\u5411C\u2082\u208a\u4ea7\u7269\u8f6c\u5316\u7684\u5173\u952e\u5728\u4e8e\u5f00\u53d1\u5177\u6709\u9ad8\u6d3b\u6027\u3001\u9ad8\u9009\u62e9\u6027\u3001\u826f\u597d\u8010\u4e45\u6027\u7684\u7535\u50ac\u5316\u5242\uff0c\u7279\u522b\u662f\u6c27\u5316\u7269\u884d\u751f\u94dc\uff08OD-Cu\uff09\u50ac\u5316\u5242\u3002OD-Cu\u5728\u5236\u5907\u8fc7\u7a0b\u4e2d\u901a\u8fc7\u4ece\u6c27\u5316\u94dc\u6676\u683c\u4e2d\u79fb\u9664\u6c27\u539f\u5b50\uff0c\u5f62\u6210\u4e30\u5bcc\u7684\u7f3a\u9677\u6676\u754c\u548c\u914d\u4f4d\u4e0d\u9971\u548c\u7684\u94dc\u4f4d\u70b9\uff0c\u8fd9\u4e9b\u72ec\u7279\u7684\u7ed3\u6784\u7279\u5f81\u80fd\u591f\u4fc3\u8fdbCO\u4e2d\u95f4\u4f53\u7684\u4e8c\u805a\u5316\uff0c\u5e76\u6709\u6548\u7a33\u5b9aC\u2082\u7269\u79cd\uff0c\u4ece\u800c\u63a8\u52a8\u53cd\u5e94\u6cbf\u7740\u751f\u6210C\u2082\u208a\u4ea7\u7269\u7684\u8def\u5f84\u8fdb\u884c\u3002\u7136\u800c\uff0c\u76ee\u524d\u62a5\u9053\u7684\u5927\u591a\u6570OD-Cu\u50ac\u5316\u5242\u4ecd\u5b58\u5728\u8f83\u5927\u5c40\u9650\u6027\uff0c\u4f8b\u5982\uff0c\u5728\u5927\u7535\u6d41\u5bc6\u5ea6\u4e0b\u9700\u8981\u8f83\u9ad8\u53cd\u5e94\u8fc7\u7535\u4f4d\u3001\u5bf9C\u2082\u208a\u4ea7\u7269\u7684\u9009\u62e9\u6027\u4e0d\u7406\u60f3\u4ee5\u53ca\u8fdb\u884c\u8868\u9762\u91cd\u6784\u7684\u8fc7\u7a0b\u76f8\u5bf9\u590d\u6742\u7b49\u3002\u4ea7\u751f\u8fd9\u4e9b\u5c40\u9650\u6027\u7684\u4e3b\u8981\u539f\u56e0\u662f\u5355\u7eaf\u4f9d\u9760CuO\/Cu\u2082O\u7535\u5316\u5b66\u8131\u6c27\u4ea7\u751f\u7684\u4e0d\u9971\u548cCu\u4f4d\u70b9\u81ea\u8eab\u96be\u4ee5\u4f18\u5316\u5173\u952e\u4e2d\u95f4\u4f53\uff08\u5982CO\u6216OC-CO\uff09\u7684\u5438\u9644\u5f3a\u5ea6\uff0c\u4e5f\u65e0\u6cd5\u6709\u6548\u63a7\u5236C\u2013C\u5076\u8054\u52a8\u529b\u5b66\u3002<\/p>\n\n\n\n

\u4ece\u5f71\u54cdC\u2013C\u5076\u8054\u52a8\u529b\u5b66\u7684\u5173\u952e\u56e0\u7d20\u51fa\u53d1\uff0c\u80fd\u6e90\u8f6c\u6362\u4e0e\u5b58\u50a8\u6750\u6599\u56e2\u961f\u7684\u7814\u7a76\u4eba\u5458\u8fd1\u671f\u8bbe\u8ba1\u4e86\u4e00\u79cd\u65b0\u578bOD-Cu\u50ac\u5316\u5242\u3002\u4ed6\u4eec\u91c7\u7528\u7b80\u4fbf\u7684\u6c34\u70ed\u6cd5\u5408\u6210\u4e86\u4e00\u79cd\u94aa\uff08Sc\uff09\u5355\u539f\u5b50\u63ba\u6742\u7684CuO\u7eb3\u7c73\u7247\uff08Sc\u2081CuO\uff09\u50ac\u5316\u5242\uff0c\u5229\u7528Sc\u8f83\u5927\u7684\u539f\u5b50\u5c3a\u5bf8\u8bf1\u53d1\u6676\u683c\u62c9\u4f38\u5e94\u53d8\uff0c\u8c03\u63a7Cu\u2013O\u952e\u957f\u548cd\u5e26\u4e2d\u5fc3\u4f4d\u7f6e\uff0c\u4ece\u800c\u6709\u6548\u589e\u5f3a\u4e86CO\u2082\u5438\u9644\u4e0e\u6d3b\u5316\u80fd\u529b\uff08\u56fe1a<\/strong>\uff09\u3002\u5f97\u76ca\u4e8e\u8fd9\u6837\u7684\u7ed3\u6784\u8bbe\u8ba1\uff0cSc\u2081CuO\u80fd\u591f\u5728\u7535\u5316\u5b66\u8fd8\u539f\u6210OD-Cu\u7684\u8fc7\u7a0b\u4e2d\u77ac\u6001\u5f62\u6210\u4e30\u5bcc\u914d\u4f4d\u4e0d\u8db3\u7684Cu0<\/sup>\u4f4d\u70b9\uff0c\u5176\u4e0e\u539f\u5b50\u7ea7\u63ba\u6742\u7684Sc\u7ed3\u5408\u5f62\u6210Sc-(O)-Cu\u6d3b\u6027\u4e2d\u5fc3\uff0c\u9a71\u52a8CO\u2082\u9009\u62e9\u6027\u5730\u8f6c\u5316\u4e3aC\u2082\u208a\u3002\u5176\u4e2d\uff0c\u5177\u6709\u6700\u4f73Sc\u63ba\u6742\u91cf\uff081.6% Sc\uff09\u7684Sc\u2081CuO-1.6\u50ac\u5316\u5242\u5728\u65bd\u52a0-0.6 V vs. RHE\u7684\u8d85\u4f4e\u7535\u4f4d\u4e0b\uff0c\u5b9e\u73b0\u4e86475.2 mA cm\u207b\u00b2\u7684\u9ad8\u7535\u6d41\u5bc6\u5ea6\uff0c\u5e76\u4e14\u5176C\u2082\u208a\u4ea7\u7269\u7684\u6cd5\u62c9\u7b2c\u6548\u7387\u9ad8\u8fbe73\u00b11.8%\uff08\u56fe1b<\/strong>\uff09\u3002\u6b64\u5916\uff0cSc\u2081CuO-1.6\u50ac\u5316\u5242\u5728-0.5 V vs. RHE\u7535\u4f4d\u4e0b\uff0c\u80fd\u591f\u4ea7\u751f~206 mA cm\u207b\u00b2\u7684\u7535\u6d41\u5bc6\u5ea6\u5e76\u6301\u7eed\u8fd0\u884c47\u5c0f\u65f6\u800c\u65e0\u6027\u80fd\u8870\u51cf\uff08\u56fe1c<\/strong>\uff09\uff0c\u5c55\u73b0\u51fa\u5353\u8d8a\u7684\u8010\u4e45\u6027\u3002\u8fdb\u4e00\u6b65\u501f\u52a9\u539f\u4f4dX\u5c04\u7ebf\u5438\u6536\u5149\u8c31\uff08\u56fe1d<\/strong>\uff09\u548c\u62c9\u66fc\u5149\u8c31\uff08\u56fe1e<\/strong>\uff09\u7b49\u5b9e\u9a8c\u624b\u6bb5\u4e0e\u5bc6\u5ea6\u6cdb\u51fd\u7406\u8bba\u8ba1\u7b97\uff08\u56fe1f<\/strong>\uff09\uff0c\u7814\u7a76\u4eba\u5458\u53d1\u73b0Sc\u63ba\u6742\u8bf1\u5bfc\u7684\u6676\u683c\u5e94\u53d8\u4e0e\u7535\u5316\u5b66\u8fd8\u539f\u5f15\u53d1\u7684\u8868\u9762\u91cd\u6784\u534f\u540c\u589e\u5f3a\u4e86CO\u2082\u7684\u5438\u9644\u4e0e\u6d3b\u5316\uff0c\u5f62\u6210\u7684Sc-(O)-Cu\u6d3b\u6027\u4e2d\u5fc3\u663e\u8457\u964d\u4f4e\u4e86C\u2013C\u5076\u8054\u80fd\u5792\uff0c\u4ece\u800c\u4fc3\u8fdbCO\u2082\u9ad8\u6548\u8fd8\u539f\u4e3aC\u2082\u208a\u4ea7\u7269\u3002\u8be5\u7814\u7a76\u5de5\u4f5c\u8bc1\u5b9e\u4e86\u7a00\u571f\u63ba\u6742\u4e0eCuO\u539f\u4f4d\u7535\u5316\u5b66\u8868\u9762\u91cd\u6784\u80fd\u6709\u6548\u540c\u65f6\u63d0\u5347CO\u2082\u8fd8\u539f\u751f\u6210C\u2082\u208a\u4ea7\u7269\u6d3b\u6027\u548c\u7a33\u5b9a\u6027\u3002<\/p>\n\n\n

\n
\"\"<\/figure><\/div>\n\n\n

\u56fe1<\/strong>.\uff08a\uff09Sc\u2081CuO\u50ac\u5316\u5242\u91cd\u6784\u540e\u62c9\u4f38\u5e94\u53d8\u4e0e\u7f3a\u9677\u5bf9CO\u2082\u8f6c\u5316\u4e3aC\u2082\u208a\u4ea7\u7269\u7684\u5173\u952e\u4f5c\u7528\u7684\u793a\u610f\u56fe\u3002Sc\u2081CuO-1.6\u50ac\u5316\u5242\uff08b\uff09\u5728\u4e0d\u540c\u7535\u4f4d\u4e0b\u5404\u4ea7\u7269\u7684\u6cd5\u62c9\u7b2c\u6548\u7387\u548c\uff08c\uff09\u5728-0.5 V vs. RHE\u4e0b\u7684\u957f\u671f\u7a33\u5b9a\u6027\u6d4b\u8bd5\u3002\uff08d\uff09\u901a\u8fc7\u539f\u4f4dX\u5c04\u7ebf\u5438\u6536\u8c31\u6d4b\u5f97\u7684\u4e0d\u540c\u7535\u4f4d\u4e0bSc\u2081CuO-1.6\u7684\u914d\u4f4d\u6570\u4e0e\u952e\u957f\u53d8\u5316\u3002\uff08e\uff09\u4e0d\u540c\u7535\u4f4d\u4e0b\u8bb0\u5f55\u7684Sc\u2081CuO-1.6\u7684\u539f\u4f4d\u8868\u9762\u589e\u5f3a\u62c9\u66fc\u5149\u8c31\u3002\uff08f\uff09\u5728\u4e0d\u540c\u6a21\u578b\u50ac\u5316\u5242\u4e0a\u53d1\u751f\u7684CO\u2082\u8fd8\u539f\u53cd\u5e94\u7684\u5409\u5e03\u65af\u81ea\u7531\u80fd\u53f0\u9636\u56fe\u3002\u5176\u4e2d\uff0c\u84dd\u8272\u3001\u7d2b\u8272\u3001\u68d5\u8272\u3001\u7ea2\u8272\u548c\u7c89\u8272\u5c0f\u7403\u5206\u522b\u4ee3\u8868\u94dc\u3001\u94aa\u3001\u78b3\u3001\u6c27\u548c\u6c22\u539f\u5b50\u3002<\/p>\n\n\n\n

\u672c\u5de5\u4f5c\u4ee5\u201cAtomic dispersion of scandium in electrochemically reduced copper oxide nanosheets for efficient electrocatalytic CO\u2082 reduction to C\u2082\u208a products\u201d\u4e3a\u9898\u4e8e2025\u5e749\u670830\u65e5\u53d1\u8868\u5728\u9886\u57df\u5185\u77e5\u540d\u671f\u520a\u300aChemical Engineering Journal\u300b\u4e0a\u3002\u80fd\u6e90\u8f6c\u6362\u4e0e\u5b58\u50a8\u6750\u6599\u56e2\u961f\u535a\u58eb\u540e\u8d75\u626c\u3001\u534e\u5357\u7406\u5de5\u5927\u5b66\u8054\u57f9\u7855\u58eb\u7814\u7a76\u751f\u66fe\u5f6c\u6587\u548c\u80fd\u6e90\u8f6c\u6362\u4e0e\u5b58\u50a8\u6750\u6599\u56e2\u961f\u526f\u7814\u7a76\u5458\u9ec4\u6d69\u91cf\u4e3a\u6587\u7ae0\u7684\u5171\u540c\u7b2c\u4e00\u4f5c\u8005\uff0c\u80fd\u6e90\u8f6c\u6362\u4e0e\u5b58\u50a8\u6750\u6599\u56e2\u961f\u5218\u5229\u5cf0\u7814\u7a76\u5458\uff0c\u534e\u5357\u7406\u5de5\u5927\u5b66\u5d14\u5fd7\u660e\u6559\u6388\u4e3a\u6587\u7ae0\u7684\u5171\u540c\u901a\u8baf\u4f5c\u8005\u3002\u677e\u5c71\u6e56\u6750\u6599\u5b9e\u9a8c\u5ba4\u4e3a\u6587\u7ae0\u7684\u7b2c\u4e00\u53ca\u901a\u8baf\u5355\u4f4d\u3002\u672c\u5de5\u4f5c\u5f97\u5230\u4e86\u79d1\u6280\u90e8\u6d77\u5916\u9ad8\u5c42\u6b21\u4eba\u624d\u5f15\u8fdb\u8ba1\u5212\uff0822J4021Z311\uff09\u548c\u56fd\u5bb6\u81ea\u7136\u57fa\u91d1\u59d4\u9752\u5e74\u79d1\u5b66\u57fa\u91d1\u9879\u76ee\uff0822309199\uff09\u7684\u8d44\u52a9\u3002<\/p>\n\n\n

\n
\"\"<\/figure><\/div>\n\n\n

\u8be5\u6587\u7ae0\u94fe\u63a5\u4e3a\uff1ahttps:\/\/www.sciencedirect.com\/science\/article\/pii\/S1385894725099759?lid=jua9g5tkojjo&utm_source=braze&utm_medium=email&utm_campaign=STMJ_220042_AUTH_SERV_PPUB&utm_content=07bab9e4-c31e-408b-afa5-1c9ca0f269ca&utm_term=07bab9e4-c31e-408b-afa5-1c9ca0f269ca&DGCID=STMJ_220042_AUTH_SERV_PPUB<\/a><\/p>\n","protected":false},"excerpt":{"rendered":"

\u5229\u7528\u53ef\u518d\u751f\u80fd\u6e90\u9a71\u52a8\u7535\u50ac\u5316\u4e8c\u6c27\u5316\u78b3\uff08CO2\uff09\u8fd8\u539f\u53ef\u4ee5\u5c06\u5927\u91cf\u4eba\u4e3a\u6392\u653e\u7684CO2\u8f6c\u5316\u4e3a\u4e59\u70ef\u3001\u4e59\u9187\u7b49\u9ad8\u9644\u52a0\u503c\u591a\u78b3\uff08C\u2082\u208a […]<\/p>\n","protected":false},"author":11,"featured_media":901,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":[],"categories":[1,4],"tags":[],"acf":[],"_links":{"self":[{"href":"https:\/\/frontbasic.sslab.org.cn\/ecsm\/wp-json\/wp\/v2\/posts\/898"}],"collection":[{"href":"https:\/\/frontbasic.sslab.org.cn\/ecsm\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/frontbasic.sslab.org.cn\/ecsm\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/frontbasic.sslab.org.cn\/ecsm\/wp-json\/wp\/v2\/users\/11"}],"replies":[{"embeddable":true,"href":"https:\/\/frontbasic.sslab.org.cn\/ecsm\/wp-json\/wp\/v2\/comments?post=898"}],"version-history":[{"count":1,"href":"https:\/\/frontbasic.sslab.org.cn\/ecsm\/wp-json\/wp\/v2\/posts\/898\/revisions"}],"predecessor-version":[{"id":902,"href":"https:\/\/frontbasic.sslab.org.cn\/ecsm\/wp-json\/wp\/v2\/posts\/898\/revisions\/902"}],"wp:featuredmedia":[{"embeddable":true,"href":"https:\/\/frontbasic.sslab.org.cn\/ecsm\/wp-json\/wp\/v2\/media\/901"}],"wp:attachment":[{"href":"https:\/\/frontbasic.sslab.org.cn\/ecsm\/wp-json\/wp\/v2\/media?parent=898"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/frontbasic.sslab.org.cn\/ecsm\/wp-json\/wp\/v2\/categories?post=898"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/frontbasic.sslab.org.cn\/ecsm\/wp-json\/wp\/v2\/tags?post=898"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}